The carboxymethylation workhorse
One reagent adds a –CH₂COOH group to cellulose, амины, phenols or thiols, which is why CMC, betaine and herbicide plants are built around it.
Monochloroacetic acid (МКА) is the standard carboxymethylating agent behind CMC, betaine surfactants, thioglycolic acid and phenoxy herbicides. СУНКЕМ поставки 99.0% мин. MCA in 25 kg bags and 1,000 кг биг-бэги, with a batch COA on every shipment.
MCA has two reactive ends: a carboxylic acid group and an activated C–Cl bond. That makes it the usual way to attach a –CH₂COOH group to cellulose, крахмал, амины, phenols and thiols. Most of the world's MCA goes into carboxymethyl cellulose (СМС). The rest feeds amphoteric surfactants, thioglycolic acid, глицин, phenoxy herbicides such as MCPA and 2,4-D, and pharmaceutical and dye intermediates.
In these reactions the by-product acids in MCA matter as much as the assay. Dichloroacetic acid (DCA) and acetic acid carry through into the downstream product, so buyers usually specify them alongside purity and moisture.

One reagent adds a –CH₂COOH group to cellulose, амины, phenols or thiols, which is why CMC, betaine and herbicide plants are built around it.
Bagged MCA is weighed and charged directly, or dissolved on site, without the heated tanks that molten MCA needs.
We quote against the limits on your incoming-inspection sheet — assay, DCA, уксусная кислота, moisture — and send the batch COA for each lot.
| Параметр | Типичное значение |
|---|---|
| Название продукта | Монохлоруксусная кислота (МКА) |
| Синонимы | Chloroacetic acid; MCAA |
| Номер КАС. | 79-11-8 |
| EC No. | 201-178-4 |
| Molecular formula | C₂H₃ClO₂ |
| Молекулярный вес | 94.50 |
| вид | White to colorless crystalline solid |
| анализ | ≥99,0% |
Assay is the typical value for our standard grade. Dichloroacetic acid (DCA), acetic acid and moisture limits depend on the producer grade and are stated on the TDS and batch COA; the limits for your order are confirmed in the quotation and contract.
Where MCA is used, and what to confirm before you switch supply.
The largest single use. Alkali cellulose is etherified with MCA or its sodium salt to make CMC for food, моющее средство, drilling-fluid and paper grades; starch is carboxymethylated the same way.
Usually neutralized to sodium chloroacetate first, MCA quaternizes fatty amidoamines to make cocamidopropyl betaine and related betaines. With sodium hydrosulfide it gives thioglycolic acid for cosmetic and PVC-stabilizer uses.
Condensed with chlorophenols to make phenoxy herbicides such as MCPA and 2,4-D, and the source of glycine used in one glyphosate route.
A building block for glycine, cyanoacetic acid and malonate esters used in caffeine and other APIs, and for dye intermediates such as phenylglycine for indigo.
| Ваше требование | Что обычно работает |
|---|---|
| СМС, betaine or herbicide production | Стандартный 99.0% мин. solid MCA |
| Your process neutralizes MCA with caustic first | Consider sodium chloroacetate (SMCA) and skip the neutralization step |
| Low by-product acids for pharma or high-purity CMC | Specify DCA and acetic acid limits; ask for the TDS before sampling |
| Charging by weight into batch reactors | Bagged solid — 25 kg bags or 1,000 кг биг-бэги |
| Replacing an existing supplier | Отправьте текущий TDS или COA; we quote against the parameters you approve |
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| Продукт | КАС | Формула | Мол. масса | When to choose |
|---|---|---|---|---|
| МКА | 79-11-8 | C₂H₃ClO₂ | 94.50 | Acid form; most CMC, herbicide and pharma routes |
| Хлорацетат натрия (SMCA) | 3926-62-3 | C₂H₂ClNaO₂ | 116.48 | Pre-neutralized; common in betaine and CMC plants that dose the salt |
Both deliver the same –CH₂COOH group. Choose by how your process is set up, and confirm with a trial.
25 kg bags or 1,000 кг биг-бэги. Tell us your pallet pattern and labeling requirements with the order.
Keep bags closed in a cool, сухой, ventilated store, away from bases, oxidizers and metals. MCA absorbs moisture and is corrosive; follow the SDS for handling and PPE.
Solid chloroacetic acid is regulated dangerous goods (И 1751, Сорт 6.1, subsidiary risk 8, PG II). Allow for DG booking and documents when you plan sea freight.
СМС, бетаин, herbicide or API: each sets different limits for DCA, acetic acid and moisture. Tell us which one and the grade you make.
Assay alone does not qualify MCA. Put DCA, уксусная кислота, moisture and, if relevant, iron on the same COA template as your incoming inspection.
Solid MCA ships as UN 1751, Сорт 6.1 (8). Согласен упаковка, labeling and the destination port early so the DG booking does not delay the first order.
Run a sample in your own process and keep the approved lot COA as the reference for contract limits.
Tell us what you make with MCA, the quantity and the destination port. Add your current specification and we will quote against it.
| Информация | Пример |
|---|---|
| Приложение | СМС, бетаин, гербицид, pharma intermediate |
| Требуемая спецификация | анализ, DCA, уксусная кислота, влага |
| Форма & упаковка | Solid · 25 kg bags or 1,000 кг биг-бэги |
| Количество | Пробный заказ / ежемесячно / годовой объем |
| Место назначения | Страна и порт |
| Необходимые документы | сертификат подлинности, паспорт безопасности, ТДС, REACH statement |
| Current supplier grade | Optional — helps us match |
Pre-neutralized MCA for betaine and CMC processes that dose the sodium salt.
Посмотреть товар →The main downstream product of MCA, for food, detergent and industrial grades.
Посмотреть товар →Amphoteric surfactant made from a fatty amidoamine and chloroacetate.
Посмотреть товар →Mainly to make carboxymethyl cellulose (СМС). It is also used for betaine surfactants, thioglycolic acid, глицин, phenoxy herbicides such as MCPA and 2,4-D, and pharmaceutical and dye intermediates.
Our standard grade is 99.0% мин. анализ. Dichloroacetic acid, acetic acid and moisture limits depend on the producer grade; we send the TDS and batch COA so you can check them against your specification before ordering.
В 25 kg bags or 1,000 кг биг-бэги. Solid chloroacetic acid is dangerous goods (И 1751, Сорт 6.1, subsidiary risk 8), so it ships with DG documents; tell us the destination port early.
If your process neutralizes MCA with caustic before the reaction, sodium chloroacetate can save that step. Plants that charge the acid directly usually stay with MCA. We can quote both.
Да. Send your application and planned test; we provide the SDS and TDS with the quotation and arrange a sample sized for your trial.